Polymers and Plastics are discussed on their own page here. Other organic chemicals will be discussed on this page.
- Weight of each component of liquid organic chemical mixtures provided different decomposition or evaporation temperature ranges
- Confirmation of a particular organic chemical compound based on its decomposition or oxidation temperature
- Weight of volatile or adsorbed organic solvents in various solid materials
Differential Scanning Calorimetry or DSC:
- Specific heat measurement
- Thermally induced reaction generating heat output
- Detection of polymorphism
- Measure the heat and temperature of crystallization upon cooling and subsequent melting temperature and latent heat upon heating
- Measure the heat of vaporization
- Detection of impurities or secondary components by distinct melting temperatures, crystallization temperatures, or by thermally stimulated reaction with the primary ingredient
- Oxidation temperature and energies
- Detect isomorphic organic components by reactions at or above the melting temperature
- Producing a phase diagram for a physical system
Thermomechanical Analysis or TMA or Dilatometry:
- Thermal expansion properties, coefficient of thermal expansion (CTE) of polymers and elastomers
- Determination of phase change temperatures in polymers such as due to glass transition temperature and crystallization
- Measure the softening temperature of a polymer
FTIR or Infrared Spectroscopy:
- Identification of bonding groups
- Identify organic chemical
- Detect changes in a chemical due to degradation
- Identify organic contaminants or additives
Contaminated Ethyl Acetate samples from the top and bottom of a large storage vessel. FTIR identified the organic contaminant.
GC-MS or Gas Chromatography – Mass Spectroscopy:
- Separates and allows the identification of many organic chemicals which may be components of a complex substance
- Measures and identifies organic contaminants in a substance
- Identifies volatile organic chemicals using Headspace Solid-Phase Micro-Extraction
- Quantitatively determine the composition for carbon, nitrogen, and elements sodium and heavier
- Detect very low concentration heavy elements down to about ten ppm
- Determine if bromine is present and if so, provides alert that further analysis for restricted brominated organic compounds is required
- Detect and measure contaminants in an organic substance provided they have distinctive elements in them, such as wear particles in oil or a chlorocarbon in a hydrocarbon
- Examine liquid drop or layer for particulates
- Examine precipitates from drying or cooling liquid
- Examine residues of evaporated liquid
- Examine filtered precipitates from drying or cooling liquid and determine the elemental composition
- Examine residues of evaporated liquid and determine the elemental composition
X-ray Photoelectron Spectroscopy or XPS or ESCA:
- Examine filtered precipitates from organic liquids, determining the elemental composition and chemistry of the particle surfaces
- Examine residues of evaporated liquids and determine the elemental composition and chemical phases in the residues
Contact Angle Measurements:
- Measures the wettability of a surface with a given liquid. Either or both the surface and the liquid may be an organic substance. The surface might be a polymer.
- Measure the surface energy or surface tension. The polar and the dispersive surface tension can be measured by using several different liquids on the surface.
- Dynamic surface tension effects can be measured as the liquid changes the properties of the surface
Density Measurements:
- Measure the density of the organic substance
- The density may indicate a contaminant or an additive